Functional Organometallic Chemistry

Design. Methodology. Application. 

About Us
We are a junior research group based in the Institute of Nanotechnology (INT) at the Karlsruhe Institute of Technology (KIT).

Our work aims to design and synthesise organometallic compounds for direct uses in catalysis, magnetism, and as bottom-up precursors for nanomaterials.

These three concepts have applications in the sustainable production of fine chemicals, quantum computing, and next level nanotechnology.

Application

Our complexes have targeted applications in Sustainable Synthesis, Quantum Computing, and Nanomaterials

Methodology

To synthesise the designed complexes, we use conventional (Schlenk Technique, Glovebox), and unconventional (Metal Vapour Synthesis, Microwave Synthesis, Mechanochemical Synthesis) anaerobic techniques.

Design

We use quantum chemical investigations such as density functional theory (DFT) to design and predict complexes with privileged electronic structures. Using an intertwined experimental and computational approach, we can look forward and develop the next generation of functional organometallics.

Thanks to a YIG Prep Pro Fellowship from KIT, we have purchased our very own glovebox, equipped with a freezer and cold well. This will allow for the storage and manipulation of air and moisture sensitive chemicals, and massively improve the efficiency of our work.


This picture shows a three-glove glovebox with equipment and chemicals inside
Carbene-activated stannylenes to access selective C(sp3)–H bond scission at the steric limit

J. Klaucke, N. Sinthathurai, C. Golz, O. P. E. Townrow,* M. Fischer,* Nat. Commun. 2025, 16, 2657, DOI: 10.1038/s41467-025-57907-2

Read More
Isolation of the Parent Triplet Titanocene via NHC Stabilization

F. Meyer, S. Demeshko, C. Golz, O. P. E. Townrow,* M. Fischer,* Dalton Trans. 2025, 54, 8035-8040, DOI: 10.1039/D5DT00480B

Read More
Tuning the Selectivity of P4 Reduction at Alkaline-Earth Metal Centres

S. Thum, O. P. E. Townrow, J. Langer, S. Harder, Chem. Sci., 2025, 16, 4528–4536. DOI: 10.1039/D4SC08502G

Read More
A Rare Case of Magnesium Alkyl Mediated CO-to-Alkoxide Conversion

O. P. E. Townrow, T. Richter, J. Langer, S. Harder, Chem. Eur. J., 2024, e202404028, DOI: 10.1002/chem.202404028

Read More
Redox-Neutral Ammonia Activation and Lithium Stannylenoid Formation Facilitated by Hemilabile Iminophosphorane-Based Ligands

D. M. J. Krengel, N. Graw, R. Herbst-Irmer, D. Stalke, O. P. E. Townrow,* M. Fischer,* Inorg. Chem. Front. 2024, 11, 8649-8659. DOI: 10.1039/D4QI02202E

Read More
Selectivity control in the reactivity of dipyrromethene gallium(I) complexes

T. Richter, S. Thum, O. P. E. Townrow, J. Langer, M. Wiesinger, S. Harder, J. Organomet. Chem. 2024, 1021, 123356. DOI: 10.1016/j.jorganchem.2024.123356

Read More
Dipyrromethene as a Ligand for the Stabilization of Low-Valent Gallium Complexes

T. Richter, S. Thum, T. Vilpas, O. P. E. Townrow, L. Klerner, J. Langer, S. Harder, Organometallics 2024, 43, 1377–1385. DOI: 10.1021/acs.organomet.4c00164

Read More
En Route to a Molecular Terminal Tin Oxide

L. Kreßner, D. Duvinage, P. Puylaert, N. Graw, R. Herbst-Irmer, D. Stalke, O. P. E. Townrow,* M. Fischer,* Inorg. Chem. 2024, 63, 7455–7463. DOI: 10.1021/acs.inorgchem.4c00598

Read More
Synthesis, Structure, and Reactivity of a Superbulky low-Valent beta-diketiminate Ga(I) Complex

T. Richter, S. Thum, O. P. E. Townrow, M. Wiesinger, J. Langer, S. Harder, Z. Anorg. Allg. Chem. 2024, 650, e202400044 DOI: 10.1002/zaac.202400044

Read More
Metal Vapour Synthesis of an Organometallic Barium(0) Synthon

O. P. E. Townrow, C. Färber, U. Zenneck, S. Harder, Angew. Chem. Int. Ed., 2023, 63, e202318428 (Hot Paper) DOI: 10.1002/anie.202318428

Read More
Controlled Cluster Expansion at a Zintl Cluster Surface

O. P. E. Townrow, A. S. Weller, J. M. Goicoechea, Angew. Chem. Int. Ed., 2023, 63, e202316120. DOI: 10.1002/anie.202316120

Read More
Thorium- and Uranium-Mediated C–H Activation of a Silyl-Substituted Cyclobutadienyl Ligand

N. Tsoureas, T. Rajeshkumar, O. P. E. Townrow, L. Maron, R. A. Layfield, Inorg. Chem., 2022, 61, 20629–20635. DOI: 10.1021/acs.inorgchem.2c03534

Read More

Dr. Oliver P. E. Townrow

Group Leader

Come and join our group!

Hiwi, Bachelor's, Master's
Please get in touch to enquire about a Hiwi position, or to write your Bachelor's or Master's thesis with us.

PhD
If you are an ambitious masters student or graduate who is interested in applying for a PhD scholarship (VCI, DAAD, DFG, Evonik Stiftung, etc.) with us, please ​let us know.

Postdoc
We are always interested in hearing from future fellows of the Alexander von Humboldt Foundation, Marie Skłodowska-Curie Actions, or similar. Please get in touch with a brief proposal outline.

All enquiries are welcome in German or English.

Fully funded positions will be posted here in the future.
Apply Now
  • Hermann-von-Helmholtz-Platz, Eggenstein-Leopoldshafen-Neureut, Germany
  • Institut für Nanotechnologie (INT), Karlsruher Institut für Technologie (KIT)